PermeateFree said:
mollwollfumble said:
I don’t know why papers like this never distinguish between acidity due to dissolved CO2, carbonic acid, and other causes of acidity. Dissolved CO2 and other acids have opposite effects, when it comes to the dissolving of sea floor carbonates for instance.
If you are that interested, why don’t you dig out the actual paper.
I told you never to say that again.
I haven’t mentioned this before because it’s really too complicated for me to understand at this point.
It’s bleedin’ obvious that increases of carbon dissolved in the ocean directly result in greater deposition of carbon from the ocean in the form of calcium carbonate – both from biological sources (corals, molluscs, forams, diatoms) and abiological sources. Currently, 50% of the carbonate deposition in the ocean is biological and 50% abiological. This is independent of the amount of calcium in the ocean because calcium at 411 ppm is present in much higher concentrations than carbon in the ocean at 28 ppm (and because the retention time for carbon in the ocean is less than that for calcium in the oceans). It’s called “conservation of mass”. So the calcium from the solution of limestone and clays on land (resulting in hard water) can be taken out of the equation.
But there’s a subtlety. Dissolved carbon in the oceans exists in three different forms: as CO 2, as CO 3 2-, and as HCO 3 -. There’s a chemical reaction CO 2 + CO 3 2- + H 2 O = 2HCO 3 -. So it can be claimed that increasing CO 2 in the oceans results in the solution of CO 3 2- off the ocean bed, a reduction of the abiological deposition.
I’m not prepared to accept that subtlety without question for two reasons. One is that a recent study showed that the biological generation of the calcium carbonate that deposits on the ocean floor can occur both from from carbon in the form of CO 2, which is the most efficient, and also from carbon in the form of HCO 3 -.
So, putting it all together, what have we got? We have that dissolving CO 2 in the oceans increases the biological generation of calcium carbonate on the ocean floor, and helps the growth of corals, molluscs, forams and diatoms. It helps the growth of plankton in general, and therefore all marine life.
But dissolving CO 2 in the oceans may temporarily reduce the abiological deposition of calcium carbonate as the balance of CO 2 + CO 3 2- = 2HCO 3 - shifts to the right until a balance is again attained. That’s what the OP paper is about.
I called it a subtlety, and the above is not particularly subtle. The rest of the subtlety is that the left-right balance of CO 2 + CO 3 2- + H 2 O = 2HCO 3 - also depends on other factors not directly related to the level of carbon dioxide in the oceans. Particularly on the amount of organic acids pouring into the oceans from the forests (more forest = more organic acids = less abiological deposition of carbonate on the ocean floor), but also on the production of sulphurous acid H 2 SO 3 that used to be produced by burning biomass and fossil fuels – before low sulphur fuels were mandated and before the installation of sulphur dioxide scrubbers in industrial plants.
This makes understanding the outcome difficult.
Have a look at this paper. It’s about the relationship between carbonate deposition and climate stability, as it relates to ice ages.
http://sci-hub.tw/http://science.sciencemag.org/content/302/5646/859.full