mollwollfumble said:
We say that desalination is energy intensive.
I can’t help wondering how the energy required for other energy intensive processes compare with each other. For starters, how does the energy requirements for each of these energy intensive processes compare?
- Desalination of seawater
- Production of table salt by evaporation of seawater
- Production of liquid oxygen and nitrogen
- Electrolysis of water to get hydrogen
- Production of aluminium
- Production of lithium
- Production of magnesium
- Production of iron
- Production of titanium
The dominant ore for aluminium is gibbsite Al2O3.3H2O
The dominant ores for lithium and magnesium are chlorides
The dominant ores for iron and titanium are oxides.
Let’s start with Gibbs free energy of formation for the metals
Desalination at 36% efficiency (best so far) is 2 kWh/m3.
… which equates to 7.2 kJ per litre.
Evaporation of water is 44 kJ/mol. (we don’t need complete evaporation to get NaCl)
The Claude cycle for liquefaction of air is 25% efficient.
Cooling air at ambient temperature requires 29.13 J/mol/K, 1 J/g/K.
Cooling air at -160˚C requires 29.57 J/mol/K, not significantly different.
So cooling air 214 degrees requires 6.3 kJ/mol.
H2O add 237.2 kJ/mol to get hydrogen and oxygen.
Al2O3 add 1576.5 kJ/mol to get aluminium and oxygen. But that’s the wrong ore.
LiCl add 383.7 kJ/mol to get lithium and chlorine.
MgCl2 add 592.5 kJ/mol to get magnesium and chlorine.
CO2 is 394.6 kJ/mol, I’ll need that for steel.
Hematite is Fe2O3 with 741 kJ/mol, the most common ore.
TiCl4 is 737.2.
TiO2 is 889.1.
Photosynthesis energy is 1883 kJ/mol of O2 evolved.