mollwollfumble said:
transition said:
was pondering, if you sketched out an objective for the replicator code, what would it be
I was thinking it need exploit energy gradients, for starters.
Indeed. Absolutely. It can’t extract energy for replication from constant temperature, or constant chemistry. It must have gradients.
Take a silicon chip for instance, without different doping chemistry you can’t get negative and positive regions so no transistors. A crystal radio relies on the surface chemistry of galena (PbS) crystals. Galena is a semiconductor with a small band gap of about 0.4 eV.
So a big plus for an inorganic replicator would be a sulphide chemistry. A computer program could be etched fairly easily onto the surface of a crystal of sulphide ore. With a place with sulphide chemistry, just add a little heat to get useful metals including copper and silver. That’s much less energy intensive than expecting a computer-style replicator to generate itself using silicon or germanium.
So, let’s get back to carbon based and non-carbon-based lifeforms.
Carbon has huge advantages over all other elements when it comes to building complex molecules at temperatures and pressures that we’re familiar with. And it’s more common than any element in the uinverse other than hydrogen and helium. So the most common minimal chemistry for a replicator is C + H.
Beyond that, it helps replicators if molecules come apart easily, and at normal temperatures and pressures that implies hydrogen bonds. For a hydrogen bond you need an electronegative atom which can be N, O, F, S or Cl. So add that as a third chemical and you’re all set.
Proteins are CHON chemicals, with S thrown into the mix as an unnecessary extra. A carbon-based replicator wouldn’t need proteins, but would need something akin to proteins. One Scifi author suggested liquid crystals as an alternative to DNA, and that is not such a stupid idea. Liquid crystals are also CHON chemicals that interact using hydrogen bonds.
A replicator has to move, and movement requires a liquid to be part of the structure under operating conditions.
Water, you ask. Well, if liquid water is present then we may as well use bacteria as replicators for seeding life. If liquid water is not present, then we have to get creative. A polar liquid is a good start, ruling out simple hydrocarbons. Alcohols can substitute for water in lower or higher temperature environments. Methanol-water mixtures can be stable liquids at temperatures down to 100 ˚C below the freezing point of water.
Carbon disulphide is another polar liquid that can substitute for water. It’s a stable liquid at ambient pressure down to -111˚C.
Low temperature liquids help out if we want to seed life not just on cold planets, but also on cold places with no atmosphere and low gravity.
Then there’s high temperature. Computer silicon chips are stable at temperatures and pressures found on the surface of Venus. But batteries can’t survive there , yet. There’s a research project to develop a battery that can survive under conditions present on the surface of Venus. Water is no good, but there is no end to large organic molecules that remain liquid under those conditions.
A liquid is needed for the replicator to move, and it can’t replicate without movement. Non-polar liquids such as liquid nitrogen, liquid oxygen, paraffins, while useful for robot lubrication, are less useful for carbon-based lifeforms.
High temperatures are also found underground. Molten salt is the easiest replacement for water under high temperature conditions. To take a few at random. Aluminium bromide is liquid between 100˚C and 250˚C. Sodium hydroxide is liquid at temperatures between 325˚C and 1385˚C. Calcium chloride is liquid at temperatures between 775˚C and 1935˚C. Choose a salt that is mineable at the destination.
PS, when seeding life, take a good drill. The centre of Pluto contains very close to the same amount of liquid water as all the oceans on Earth. Which could give it an ecosystem as big as Earth’s.
One further option.
One author has suggested making a replicator out of clay/mica. Clay/mica consists of a sequence of single sheets with electric charges on them. Lining up the charges allows replication given successive cycles of wetting and dehydration. I’m not a particular fan of that but it does point out an alternative to linear replication (DNA and liquid crystals).
The advantage of clay/mica as a replicator is that it eliminates the need for carbon, being made of Mg, Al, Si, O, H.
Some talk of silicon or sulphur as a replacement for carbon. But I have yet to see any evidence that they can be used to build linear macromolecules like carbon. Perhaps in some exotic temperature-pressure domain they can.
The element sequence that is available as raw materials in the universe for building a replicator is quite well known. In sequence it is:
H, O, Si, Na, Al, Ca, K, Fe, Mg, Ti, F, C, P, Mn, S, Sr, Ba, Cl, N.
So nitrogen and carbon (and P and S) are actually a fair way down the list – except in the early universe when heavier elements would have been less abundant. That makes Si-based replicators a worthwhile research topic, but only in areas with low oxygen.
The ratio changes a lot for the surfaces of planets and moons.