The rules of optimal metabolism say that it is better to consume the bulk of your kilojoules during the first half of the day. This means that 2pm or 3pm is too late to eat lunch.
From this article:
http://www.dailylife.com.au/health-and-fitness/dl-nutrition/this-is-what-an-ideal-days-eating-looks-like-20130422-2i992.html
Is there any possible scientific theory to back that up?