From another forum
I found it on the internet so it must be true.
The neck ring of the Apollo A7L suit was originally anodized blue in color. During use of the A7L suit, a design change was made to the vent port between the suit neck ring and the helmet. This change enlarged the vent port and slightly clocked its position on the neck ring. The color of the neck ring was changed from blue to red to make a clear distinction between the two vent port designs.
Thus an early (blue) A7L helmet would not get adequate vent flow on a later (red) neck ring suit and vise versa due to the changes in size and position of the vent port. A helmet with a blue neck ring will actually latch into a red suit neck ring but the vent ports will be misaligned. The first use of A7L suits with red neck rings was on the Apollo 11 mission. All subsequent A7L suits used the red neck rings as well as the A7LB suits.
The Apollo suit-side neck ring is actually made up of multiple parts, and all of them were initially anodized blue. When the vent port design change was made only the outer shell of the suit-side neck ring was changed in color from blue to red. All the other parts of the suit-side neck ring (with the exception of the suit-side vent port which was also changed from blue to red) remained blue. This is why the inside of a red suit-side neck ring is blue.
Further, the red neck rings included engraved wording stating that a red helmet neck ring should only be used with a red suit neck ring. Similar wording was on the red suit neck rings as well.
Crew photos were not necessarily taken with the crew wearing their flight spacesuit. Thus crew photos usually show a mix of neck ring colors as they used the suits that were available at the time of the photo.
In addition, crew training used whatever suits were available at the time. Only flight-day walk-out or in-flight photos will show what was actually used on the mission.
One additional note: In the Apollo 11 crew photo, only Collins is holding a helmet, both Armstrong and Aldrin are holding the LEVA without the helmets inside. The “red” color visible inside Armstrong’s LEVA is the interior of the LEVA shell which is red colored plastic.